% IMPORTANT: The following is UTF-8 encoded. This means that in the presence % of non-ASCII characters, it will not work with BibTeX 0.99 or older. % Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or % “biber”. @PHDTHESIS{ElWajeh:1009405, author = {El Wajeh, Mohammad}, othercontributors = {Mitsos, Alexander and Swartz, Christopher L. E.}, title = {{O}ptimal dynamic operation of electrified biodiesel production}, volume = {36}, school = {Rheinisch-Westfälische Technische Hochschule Aachen}, type = {Dissertation}, address = {Aachen}, publisher = {RWTH Aachen University}, reportid = {RWTH-2025-03483}, series = {Aachener Verfahrenstechnik series - AVT.SVT - Process systems engineering}, pages = {1 Online-Ressource : Illustrationen}, year = {2025}, note = {Veröffentlicht auf dem Publikationsserver der RWTH Aachen University; Dissertation, Rheinisch-Westfälische Technische Hochschule Aachen, 2025}, abstract = {The flexible operation of electrified chemical processes powered by renewable electricity offers both economic and ecological benefits, contributing to more sustainable chemical production. However, transitioning from conventional steady-state operations presents a significant challenge to process design and operation. While this change in operational paradigm paves the way for achieving optimal flexible operation and effective demand-side management, it also necessitates incorporating process dynamics into scheduling decisions to ensure both optimal and feasible outcomes. This is particularly relevant for chemical plants, such as biodiesel production processes, which operate on time scales comparable to fluctuations in electricity prices. In this dissertation, we develop and implement modeling- and optimization-based methods and tools to address key aspects of optimal dynamic operations in electrified chemical processes. We develop and apply a modeling and optimization framework that guides process systems through essential stages to achieve the final goal of optimal flexible operation for an electrified biodiesel production process. The dissertation chapters are structured around these main stages, beginning with model development, followed by electrification and offline optimization with process design considerations, and concluding with online control. We begin with the model development phase, where we introduce a rigorous mechanistic dynamic model of the biodiesel production process, along with two plantwide base-layer control structures. We simulate plant responses under various disturbances to highlight the necessity of model-based control strategies in meeting operational goals. This model serves as the foundation for the subsequent chapters. Moving to the offline optimization stage, we formulate dynamic optimization problems that incorporate flexibility-oriented process designs. We demonstrate the dual role of buffer tanks for storing intermediate and final products, which not only enhance operational flexibility but also enable system decomposition for distributed optimization by decoupling dynamics between different process sections. Additionally, we explore the impact of heat integration on operational flexibility and demonstrate how incorporating additional electrified heating units increases the degrees of freedom in optimization. Building on the offline studies and flexibility-oriented process configurations, we then move to the final stage—online control—where we implement real-time control applications. In particular, we leverage the process configuration that supports distributed optimization to develop and apply distributed economic nonlinear model predictive control. Our distributed control strategies incorporate both sequential and iterative communication architectures, as well as compensation schemes for computational delays. These schemes account for subsystem couplings and delays across multiple sampling intervals. By systematically progressing through these three stages, we achieve the final objective of optimal and feasible flexible operation for chemical processes. This dissertation not only demonstrates the interconnectivity between these stages during both development and implementation but also provides methods and tools with broad applicability to other chemical processes targeting optimal dynamic operations.}, cin = {416710}, ddc = {620}, cid = {$I:(DE-82)416710_20140620$}, pnm = {BMBF 03SFK3L1 - Kopernikus-Projekt SynErgie (03SFK3L1)}, pid = {G:(DE-82)03SFK3L1}, typ = {PUB:(DE-HGF)11 / PUB:(DE-HGF)3}, doi = {10.18154/RWTH-2025-03483}, url = {https://publications.rwth-aachen.de/record/1009405}, }