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@PHDTHESIS{ElWajeh:1009405,
      author       = {El Wajeh, Mohammad},
      othercontributors = {Mitsos, Alexander and Swartz, Christopher L. E.},
      title        = {{O}ptimal dynamic operation of electrified biodiesel
                      production},
      volume       = {36},
      school       = {Rheinisch-Westfälische Technische Hochschule Aachen},
      type         = {Dissertation},
      address      = {Aachen},
      publisher    = {RWTH Aachen University},
      reportid     = {RWTH-2025-03483},
      series       = {Aachener Verfahrenstechnik series - AVT.SVT - Process
                      systems engineering},
      pages        = {1 Online-Ressource : Illustrationen},
      year         = {2025},
      note         = {Veröffentlicht auf dem Publikationsserver der RWTH Aachen
                      University; Dissertation, Rheinisch-Westfälische Technische
                      Hochschule Aachen, 2025},
      abstract     = {The flexible operation of electrified chemical processes
                      powered by renewable electricity offers both economic and
                      ecological benefits, contributing to more sustainable
                      chemical production. However, transitioning from
                      conventional steady-state operations presents a significant
                      challenge to process design and operation. While this change
                      in operational paradigm paves the way for achieving optimal
                      flexible operation and effective demand-side management, it
                      also necessitates incorporating process dynamics into
                      scheduling decisions to ensure both optimal and feasible
                      outcomes. This is particularly relevant for chemical plants,
                      such as biodiesel production processes, which operate on
                      time scales comparable to fluctuations in electricity
                      prices. In this dissertation, we develop and implement
                      modeling- and optimization-based methods and tools to
                      address key aspects of optimal dynamic operations in
                      electrified chemical processes. We develop and apply a
                      modeling and optimization framework that guides process
                      systems through essential stages to achieve the final goal
                      of optimal flexible operation for an electrified biodiesel
                      production process. The dissertation chapters are structured
                      around these main stages, beginning with model development,
                      followed by electrification and offline optimization with
                      process design considerations, and concluding with online
                      control. We begin with the model development phase, where we
                      introduce a rigorous mechanistic dynamic model of the
                      biodiesel production process, along with two plantwide
                      base-layer control structures. We simulate plant responses
                      under various disturbances to highlight the necessity of
                      model-based control strategies in meeting operational goals.
                      This model serves as the foundation for the subsequent
                      chapters. Moving to the offline optimization stage, we
                      formulate dynamic optimization problems that incorporate
                      flexibility-oriented process designs. We demonstrate the
                      dual role of buffer tanks for storing intermediate and final
                      products, which not only enhance operational flexibility but
                      also enable system decomposition for distributed
                      optimization by decoupling dynamics between different
                      process sections. Additionally, we explore the impact of
                      heat integration on operational flexibility and demonstrate
                      how incorporating additional electrified heating units
                      increases the degrees of freedom in optimization. Building
                      on the offline studies and flexibility-oriented process
                      configurations, we then move to the final stage—online
                      control—where we implement real-time control applications.
                      In particular, we leverage the process configuration that
                      supports distributed optimization to develop and apply
                      distributed economic nonlinear model predictive control. Our
                      distributed control strategies incorporate both sequential
                      and iterative communication architectures, as well as
                      compensation schemes for computational delays. These schemes
                      account for subsystem couplings and delays across multiple
                      sampling intervals. By systematically progressing through
                      these three stages, we achieve the final objective of
                      optimal and feasible flexible operation for chemical
                      processes. This dissertation not only demonstrates the
                      interconnectivity between these stages during both
                      development and implementation but also provides methods and
                      tools with broad applicability to other chemical processes
                      targeting optimal dynamic operations.},
      cin          = {416710},
      ddc          = {620},
      cid          = {$I:(DE-82)416710_20140620$},
      pnm          = {BMBF 03SFK3L1 - Kopernikus-Projekt SynErgie (03SFK3L1)},
      pid          = {G:(DE-82)03SFK3L1},
      typ          = {PUB:(DE-HGF)11 / PUB:(DE-HGF)3},
      doi          = {10.18154/RWTH-2025-03483},
      url          = {https://publications.rwth-aachen.de/record/1009405},
}