Mechanistic Understanding of The Photoexcited Nitroarene-Mediated Olefin Ozonolysis
Grant period
2024-06-03 - 2026-06-02
Funding body
European Union
CORDIS
Call number
HORIZON-MSCA-2023-PF-01
Grant number
101150311
Identifier
G:(EU-Grant)101150311
Note:
Photoexcited nitroarenes as ozone surrogates in olefin ozonolysis. Olefins are commonly converted by olefin ozonolysis into synthetic intermediates including aldehydes, ketones and carboxylic acids for the bulk chemical industry. Concerns regarding ozone safety have prohibited use of this reaction by fine chemical sectors including the pharmaceutical and agrochemical industries. Recent demonstration that photoexcited nitroarenes can be used as ozone surrogates for the oxidative cleavage of olefins opens the door to use by the fine chemical industry. With the support of the Marie Skłodowska-Curie Actions programme, the NOZONE project aims to make this possible by characterising the key mechanisms governing reactivity.
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