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@PHDTHESIS{Acikalin:51375,
      author       = {Acikalin, Serdar},
      othercontributors = {Gais, Hans-Joachim},
      title        = {{E}nantioselective synthesis of cyclic beta-amino alcohols
                      via tandem hydroalumination-cyclization-reduction of
                      ethoxycarbonyl vinyl sulfoximines and application to the
                      synthesis of potential aggrecanase inhibitors},
      address      = {Aachen},
      publisher    = {Publikationsserver der RWTH Aachen University},
      reportid     = {RWTH-CONV-113674},
      pages        = {154 S. : graph. Darst.},
      year         = {2009},
      note         = {Aachen, Techn. Hochsch., Diss., 2009},
      abstract     = {The beta-amino alcohol moiety is a common structural
                      component in a wide variety of natural occurring compounds,
                      synthetic pharmacologically important molecules, ligands and
                      chiral auxiliaries for asymmetric synthesis. Due to the fact
                      that the stereochemistry of the beta-amino alcohol moiety is
                      important for biological activity and for chirality
                      transfer, asymmetric synthesis of compounds containing
                      beta-amino alcohol functionality has drawn considerable
                      attention. This thesis describes enantioselective synthesis
                      of cyclic beta-amino alcohols starting from ethoxycarbonyl
                      vinyl sulfoximines, which are prepared from cyclic
                      bis(allylsulfoximine)titanium complexes and
                      N-tert-butylsulfonyl alpha-imino ester. The application of
                      sulfoximine substituted bicyclic 1,2-amino alcohol in the
                      synthesis of potential aggrecanase inhibitor is described.},
      keywords     = {Asymmetrische Synthese (SWD) / Sulfoximin (SWD) /
                      Alkanolamine (SWD)},
      cin          = {150000 / 152510},
      ddc          = {540},
      cid          = {$I:(DE-82)150000_20140620$ / $I:(DE-82)152510_20140620$},
      shelfmark    = {VK 5070},
      typ          = {PUB:(DE-HGF)11},
      urn          = {urn:nbn:de:hbz:82-opus-29728},
      url          = {https://publications.rwth-aachen.de/record/51375},
}