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TY - THES AU - Woo, Chang-Wan TI - Asymmetrische Synthese funktionalisierter Homoallyl- und Homopropargylalkohole mittels der Sulfoximin-Route CY - Aachen PB - Publikationsserver der RWTH Aachen University M1 - RWTH-CONV-121920 SP - VIII, 205 S. PY - 2000 N1 - Aachen, Techn. Hochsch., Diss., 2000 AB - This dissertation describes new methods of asymmetric synthesis of diastereomeric and enantiomeric pure allylic alcohols. Via the sulfoximine-route by Gais et al. new chiral homoallyllic alcohols were synthesized. Elimination of the sulfoximine-group lead to optically pure homopropargylic alcohols. Via Nickel-catalysed cross-coupling reactions (homogenoes and heterogenoes Catalysis) of the homoallylic alcohols additional allylic silane- and allylic alcohol- groups were generated. Intramolecular cyclisation of the chiral allylic silanes with acetals yielded optically pure tetrasubstituted tetrahydrofurans. LB - PUB:(DE-HGF)11 UR - https://publications.rwth-aachen.de/record/60197 ER -