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000762101 001__ 762101 000762101 005__ 20240701081739.0 000762101 0247_ $$2datacite_doi$$a10.18154/RWTH-2019-05397 000762101 037__ $$aRWTH-2019-05397 000762101 041__ $$aEnglish 000762101 1001_ $$0P:(DE-82)729328$$aKsiazkiewicz, Agnieszka$$b0 000762101 245__ $$aData Set to „Closing the 1-5 µm Size Gap: Temperature-programmed, Fed-batch Synthesis of µm-sized Microgels” 000762101 260__ $$c2019 000762101 3367_ $$2BibTeX$$aMISC 000762101 3367_ $$0PUB:(DE-HGF)32$$2PUB:(DE-HGF)$$aDataset$$bdataset$$mdataset$$s1563879830_67650 000762101 3367_ $$026$$2EndNote$$aChart or Table 000762101 3367_ $$2DataCite$$aDataset 000762101 3367_ $$2ORCID$$aDATA_SET 000762101 3367_ $$2DINI$$aResearchData 000762101 520__ $$aMicrogels below 1 µm and above 20 µm are readily accessible; however, obtaining them in size 1-10 µm still remains a challenge. We present a surfactant-free precipitation polymerization approach, combining temperature-ramp (T-ramp) and fed-batch, generating 1-5 µm in diameter poly(N-Vinylcaprolactam) (pVCL) microgels. Confocal microscopy and dynamic light scattering (DLS) confirm that the size of temperature-responsive pVCL microgels can be adjusted by the feeding ratio. The experimentally determined microgel sizes match well the model-based predictions. The developed synthesis method achieves high monomer conversions and provides high microgel yields as determined by Raman spectroscopy. 000762101 536__ $$0G:(GEPRIS)221473487$$aSFB 985 B04 - Synthese von Mikrogelen: Kinetik, Partikelbildung und Reaktordesign (B04) (221473487)$$c221473487$$x0 000762101 536__ $$0G:(GEPRIS)191948804$$aDFG project 191948804 - SFB 985: Funktionelle Mikrogele und Mikrogelsysteme (191948804)$$c191948804$$x1 000762101 591__ $$aGermany 000762101 591__ $$aNetherlands 000762101 653_7 $$aMicrogels 000762101 7001_ $$0P:(DE-82)IDM03320$$aBering, Luise$$b1$$urwth 000762101 7001_ $$0P:(DE-82)IDM03100$$aJung, Falco Constantin$$b2$$urwth 000762101 7001_ $$0P:(DE-HGF)0$$aWolter, Nadja Anna$$b3 000762101 7001_ $$0P:(DE-82)IDM00357$$aViell, Jörn$$b4$$urwth 000762101 7001_ $$0P:(DE-82)IDM00369$$aMitsos, Alexander$$b5$$urwth 000762101 7001_ $$0P:(DE-82)IDM00066$$aPich, Andrij$$b6$$eCorresponding author$$urwth 000762101 7870_ $$0RWTH-2019-07407$$aKsiazkiewicz, Agnieszka Natalia et.al.$$dAmsterdam : Elsevier, 2019$$iRelatedTo$$tClosing the 1-5 µm Size Gap: Temperature-programmed, Fed-batch Synthesis of µm-sized Microgels 000762101 8564_ $$uhttps://publications.rwth-aachen.de/record/762101/files/model_modelica.zip$$yOpenAccess 000762101 909CO $$ooai:publications.rwth-aachen.de:762101$$pdriver$$pVDB$$popen_access$$popenaire 000762101 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess 000762101 915__ $$0LIC:(DE-HGF)CC0$$2HGFVOC$$aCC0: Public Domain Dedication 000762101 9141_ $$y2019 000762101 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-82)IDM03100$$aRWTH Aachen$$b2$$kRWTH 000762101 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-82)IDM00357$$aRWTH Aachen$$b4$$kRWTH 000762101 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-82)IDM00369$$aRWTH Aachen$$b5$$kRWTH 000762101 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-82)IDM00066$$aRWTH Aachen$$b6$$kRWTH 000762101 9201_ $$0I:(DE-82)416710_20140620$$k416710$$lLehrstuhl für Systemverfahrenstechnik$$x0 000762101 961__ $$c2019-07-23T13:18:01.392672$$x2019-06-03T16:05:42.042050$$z2019-07-23T13:18:01.392672 000762101 9801_ $$aFullTexts 000762101 980__ $$adataset 000762101 980__ $$aVDB 000762101 980__ $$aUNRESTRICTED 000762101 980__ $$aI:(DE-82)416710_20140620