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@PHDTHESIS{Walch:794983,
      author       = {Walch, Emmanuel},
      othercontributors = {Roos, Christian Hans-Georg and Rädlein, Edda},
      title        = {{I}nvestigation of the mechanical properties of a connector
                      - silver - enamel - float glass composite},
      school       = {Rheinisch-Westfälische Technische Hochschule Aachen},
      type         = {Dissertation},
      address      = {Aachen},
      reportid     = {RWTH-2020-08013},
      pages        = {1 Online-Ressource (XIV, 145 Seiten) : Illustrationen,
                      Diagramme},
      year         = {2020},
      note         = {Veröffentlicht auf dem Publikationsserver der RWTH Aachen
                      University; Dissertation, Rheinisch-Westfälische Technische
                      Hochschule Aachen, 2020},
      abstract     = {Heated automotive backlights are composed of the
                      soda-lime-silicates glass substrate, the enamel and silver
                      thick films, and several lead-free soldered connectors. The
                      challenges faced with this composite stack are significant
                      cumulated degradations of the initial glass strengths by the
                      subsequent addition of layers and connectors. SEM
                      fractographic analyses undertaken on the composite stack
                      have revealed that fracture originates in the enamel layer
                      and more precisely the region near the interface with
                      sintered silver. The soda-lime silicate glass and enamel
                      glass frit were found to have comparable values while the
                      fracture toughness of sintered silver has been found to be
                      one order of magnitude higher. The most critical defects of
                      the stack are located in the enamel, due to their relatively
                      large size, and the fragile nature of this layer.
                      Additionally, the amount of compressive residual stress in
                      the enamel film is lower compared to the surface of the
                      tempered glass substrate. Finally, the soldering of the
                      connector transfers tensile stresses in the brittle part of
                      the stack. Therefore, tensile stresses are applied to the
                      porosities present in the enamel. Theses porosities act as
                      stress concentrators, facilitating the propagation of cracks
                      which in turn decreases drastically the mechanical strength
                      of the composite stack. In the case of high tensile
                      soldering stresses, several cracks can propagate in the
                      enamel from pre-existing critical defects and propagates to
                      the glass, leading to the formation of glass chipping in the
                      glass substrate. The formation and growth of large glass
                      chips can lead to spontaneous breakage of the backlights.
                      The soldering process has the highest influences, among the
                      process parameter, onto the mechanical strength of the
                      composite stack. The robustness of the automotive backlight
                      can be increased by reducing the amount and size of
                      porosities in the enamel layer and by optimizing the
                      residual stresses in the stack.},
      cin          = {524210 / 520000},
      ddc          = {620},
      cid          = {$I:(DE-82)524210_20140620$ / $I:(DE-82)520000_20140620$},
      typ          = {PUB:(DE-HGF)11},
      doi          = {10.18154/RWTH-2020-08013},
      url          = {https://publications.rwth-aachen.de/record/794983},
}