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000797385 001__ 797385
000797385 005__ 20230221044816.0
000797385 0247_ $$2CORDIS$$aG:(EU-Grant)864849$$d864849
000797385 0247_ $$2CORDIS$$aG:(EU-Call)ERC-2019-COG$$dERC-2019-COG
000797385 0247_ $$2originalID$$acorda__h2020::864849
000797385 035__ $$aG:(EU-Grant)864849
000797385 150__ $$aMetalloradical Catalysis - From Fundamental Studies to Applications$$y2020-05-01 - 2025-10-31
000797385 371__ $$aRWTH Aachen University$$bRWTH$$dGermany$$ehttp://www.rwth-aachen.de/cms/~a/root/lidx/1/$$vCORDIS
000797385 372__ $$aERC-2019-COG$$s2020-05-01$$t2025-10-31
000797385 450__ $$aMetalloRadiCat$$wd$$y2020-05-01 - 2025-10-31
000797385 5101_ $$0I:(DE-588b)5098525-5$$2CORDIS$$aEuropean Union
000797385 680__ $$aOver the past decades, metal catalysis has had a tremendous impact in chemistry, its adjacent disciplines and society overall, having gained an omnipresence in academic and industrial research worldwide. Numerous previously unthinkable transformations can nowadays be achieved in a selective and relatively mild manner owing to the metals' unique ability to trigger bond-making and breaking via pathways and principles that are inaccessible to metal-free processes. In this context, the global community has focused primarily on closed-shell, two electron processes for synthetic transformations. By comparison, the field of metalloradical catalysis has seen much less development, although metalloradicals are nature's preferred species to tame radical reactivities under non-precious metal-catalysis in numerous metalloenzymes. This is likely due to our currently limited understanding of metalloradical reactivity and its associated principles, and as such also limited ability to rationally design metalloradical catalysts and catalytic processes. A multidisciplinary approach, which capitalizes on the principles and insights of organic, organometallic and biological processes, will likely be key to meet the next frontier in this promising field. The objective of this proposal is to combine the tools of mechanistic, computational and synthetic organic/organometallic chemistry to explore catalysis with metalloradicals in synthesis, materials research and enzymatic processes. The proposed program will investigate some of the most pertinent questions in relation to the emerging area of remote functionalizations for the selective synthetic access to tailored molecules, olefin migrations and manipulations, and naturally occurring (enzymatic) metalloradical-catalyzed processes in the context of methane production and activation.
000797385 909CO $$ooai:juser.fz-juelich.de:879832$$pauthority$$pauthority:GRANT
000797385 909CO $$ooai:juser.fz-juelich.de:879832
000797385 970__ $$aoai:dnet:corda__h2020::ca5d5859745f60b2b1d5689f43cd467a
000797385 980__ $$aG
000797385 980__ $$aCORDIS
000797385 980__ $$aAUTHORITY