TY - THES AU - Nothdurft, Katja TI - Cononsolvency of microgels : equilibrium and dynamics PB - RWTH Aachen University VL - Dissertation CY - Aachen M1 - RWTH-2021-08634 SP - 1 Online-Ressource : Illustrationen PY - 2021 N1 - Veröffentlicht auf dem Publikationsserver der RWTH Aachen University N1 - Dissertation, RWTH Aachen University, 2021 AB - Microgels are three-dimensional, cross-linked polymeric networks swollen by a good solvent. Poly-N-isopropylacrylamide (PNIPAM)-based materials are of ongoing scientific interest due to their unique responsive behavior to external parameters such as temperature and solvent composition. Although PNIPAM microgels are the subject of a variety of application-oriented studies, fundamental aspects about the underlying processes of the responsive behavior are still under discussion. The present work focuses on the sensitivity of PNIPAM to the composition of water-methanol mixtures, the so-called cononsolvency effect. Here, the gels are swollen in either of the pure solvents, whereas water-rich mixtures around 20 mol LB - PUB:(DE-HGF)11 DO - DOI:10.18154/RWTH-2021-08634 UR - https://publications.rwth-aachen.de/record/825952 ER -