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@PHDTHESIS{Kollath:888691,
      author       = {Kollath, John Mark Albert},
      othercontributors = {Oppel, Iris Marga and Simon, Ulrich},
      title        = {{A}ufbau von {K}oordinationsverbindungen aus
                      {C}$_{3}$-symmetrischen {L}iganden und deren {R}eaktion mit
                      {G}oldclustern},
      school       = {RWTH Aachen University},
      type         = {Dissertation},
      address      = {Aachen},
      publisher    = {RWTH Aachen University},
      reportid     = {RWTH-2023-00747},
      pages        = {1 Online-Ressource : Illustrationen, Diagramme},
      year         = {2022},
      note         = {Veröffentlicht auf dem Publikationsserver der RWTH Aachen
                      University 2023; Dissertation, RWTH Aachen University, 2022},
      abstract     = {Supramolecular cyclic coordination oligomers developed in
                      the working group are excellent hosts for fullerene guest
                      molecules as C60 and C70. It is therefore interesting to
                      explore, whether other guest compounds of comparable size,
                      such as gold clusters, can be stabilized in these host
                      structures, as well. Therefore, the reaction of cyclic
                      coordination oligomers with different gold compounds, i.e.
                      triphenyl phosphine (TPP) Au(I)-complexes, TPP stabilized
                      Au9- and Au55-clusters was investigated. Surprisingly, it
                      could be observed that the reaction, irrespective of the
                      starting compounds, resulted in the formation of
                      TPP-stabilized Au11-clusters, comprising slight structural
                      variations, but having a cluster core size complementary to
                      the cyclic coordination oligomers cavity. In this
                      dissertation the results and the attempts in understanding
                      these unexpected findings are shown. Various coordination
                      compounds such as dimers, triple and quadruple layer
                      structures are used to investigate the influence of cavities
                      and interactions.},
      cin          = {151520 / 150000},
      ddc          = {540},
      cid          = {$I:(DE-82)151520_20140620$ / $I:(DE-82)150000_20140620$},
      typ          = {PUB:(DE-HGF)11},
      doi          = {10.18154/RWTH-2023-00747},
      url          = {https://publications.rwth-aachen.de/record/888691},
}