% IMPORTANT: The following is UTF-8 encoded. This means that in the presence % of non-ASCII characters, it will not work with BibTeX 0.99 or older. % Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or % “biber”. @PHDTHESIS{Suer:963309, author = {Suer, Julian}, othercontributors = {Traverso, Marzia and Deike, Rüdiger}, title = {{G}reen steel - life cycle modeling of an integrated steel site : carbon footprint and energy transformation analysis of decarbonized steel production}, school = {Rheinisch-Westfälische Technische Hochschule Aachen}, type = {Dissertation}, address = {Aachen}, publisher = {RWTH Aachen University}, reportid = {RWTH-2023-07732}, pages = {1 Online-Ressource : Illustrationen, Diagramme}, year = {2023}, note = {Veröffentlicht auf dem Publikationsserver der RWTH Aachen University; Dissertation, Rheinisch-Westfälische Technische Hochschule Aachen, 2023, Kumulative Dissertation}, abstract = {The steel industry is focused on reducing its environmental impact. Steel is typically produced primarily from iron ores in integrated sites and secondarily from scrap recycling in electric arc furnaces (EAF). Traditional integrated sites include hot metal generation via the blast furnace route, basic oxygen steelmaking (BOF), continuous casting, and subsequent hot-rolling. For the evaluation of environmental impacts generated by the product, the life cycle assessment (LCA) methodology according to ISO 14040/44 has been used. The LCA is internationally recognized and standardized. Using the LCA methodology, the impacts of primary steel production via the blast furnace route and the secondary scrap-based steel production via the EAF route are assessed. These production routes represent the state-of-the art. Subsequently, decarbonization strategies are analysed using the product carbon footprint (PCF) methodology according to ISO 14067. In a blast furnace coal and coke are used for the reduction and melting of iron ores. The decarbonization of the steel industry requires a shift from a coal-based metallurgy towards a hydrogen and electricity-based steel production, or purely electric, if the utilized hydrogen stems from electrolysis. The blast furnace can be substituted by direct reduction (DR) plants with subsequent electrical melting. In DR plants, iron oxides can be reduced by natural gas as well as pure hydrogen. DR plants have reached capacities, which allow replacing blast furnaces on a direct basis. While the majority of European steel producers have pointed to direct reduced iron (DRI) production as a key part of their decarbonization targets, the next steps are highly discussed. Two main routes stand out: (1) Melting and processing the DRI in an EAF directly to crude steel; (2) Melting and carburizing the DRI in an electric melting unit to hot metal. The hot metal is then further refined in a BOF to crude steel. Whereas the first route seems to be more straightforward, some metallurgical points require discussion. On the basis of the carbon footprint methodology different scenarios of a stepwise transition are evaluated and values of possible CO2equivalent (CO2eq) reduction are coupled with the demand of hydrogen, electricity, natural gas, and coal. For example, while the traditional blast furnace - BOF route delivers a surplus of electricity in the range of 0.7 MJ/kg hot-rolled coil; this surplus turns into a deficit of about 17 MJ/kg hot-rolled coil for a hydrogen-based steel production route. On the other hand, while the product carbon footprint of the blast furnace-related production route is 2.1 kg CO2eq/kg hot-rolled coil; this footprint can be reduced to 0.75 kg CO2eq/kg hot-rolled coil for the hydrogen-related route, obtained with electricity input generated by renewable sources. Thereby the direct impact of the processes of the integrated site can even be reduced to 0.15 kg CO2eq/kg hotrolled coil. The remaining carbon footprint is caused by upstream processes for which no improvements are considered. However, if the electricity input has a carbon footprint related to the German or European electricity grid mix, the respective carbon footprint of hot-rolled coil increases up to 3.0 kg CO2eq/kg hot-rolled coil. A natural gas-based DR production route leads to a carbon footprint of 1.4 - 1.7 kg CO2eq/kg hot-rolled coil, depending on the electricity mix used for the steel production processes. A detailed break-even analysis is given, comparing the use of natural gas and hydrogen using different electricity mixes. Intermediate scenarios can enable a stepwise transition of changed plant configurations and material and energy related feedstocks. Simultaneously, the intermediate scenarios lead to PCF reductions in time. In this dissertation the scenarios hydrogen and natural gas injection into a blast furnace and the use of hot briquetted iron (HBI) in a blast furnace are analyzed.}, cin = {316710}, ddc = {624}, cid = {$I:(DE-82)316710_20180607$}, typ = {PUB:(DE-HGF)11}, doi = {10.18154/RWTH-2023-07732}, url = {https://publications.rwth-aachen.de/record/963309}, }