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@MISC{Pielsticker:992258,
author = {Pielsticker, Stefan and Hendricks, Katja and Kneer,
Reinhold},
title = {{F}ourier-transform infrared ({FTIR}) spectra of gaseous
methyl methacrylate ({MMA})},
reportid = {RWTH-2024-08098},
year = {2024},
abstract = {Polymethyl methacrylate (PMMA) is a transparent and rigid
thermoplastic polymer often used as a lightweight
alternative to quartz glass. Within the context of plastic
recycling and a circular economy, pyrolysis of PMMA is a
promising process to recover the monomer unit MMA from the
polymer. For quantitatively determining the released
products under various reaction conditions, a suitable
method based on the analysis of the gas phase is required.
Fourier-transform infrared spectroscopy is a suitable
technique for quantitatively specifying a broad spectrum of
the resulting pyrolysis products. However, to be able to
close the mass balance properly, the primary pyrolysis
product MMA must also be correctly quantified in the gas
analysis. The following data set includes FTIR reference
spectra recorded for MMA/N2 gas mixtures with MMA volume
fractions in the range 3626–145087 ppm generated with an
evaporation/condensation setup. Spectra are recorded with an
Ansyco GASMET DX-2000 (2.0 m optical path length) in the
spectral range of 600–4200 $cm^-1$ (8 $cm^-1$ spectral
resolution) for a cell temperature of 453 K and atmospheric
pressure.},
cin = {412610},
cid = {$I:(DE-82)412610_20140620$},
pnm = {PFKA008 - Cluster 4 Plastics Recycling (EXS-PF-PFKA008) /
ERS Prep Fund - Exploratory Research Space: Prep Fund als
Anschubfinanzierung zur Schließung strategischer Lücken
(EXS-PF) / EXS - Excellence Strategy (EXS)},
pid = {G:(DE-82)EXS-PF-PFKA008 / G:(DE-82)EXS-PF / G:(DE-82)EXS},
typ = {PUB:(DE-HGF)32},
doi = {10.18154/RWTH-2024-08098},
url = {https://publications.rwth-aachen.de/record/992258},
}